The core of planetary nebula NGC 6302 is filled with high-excitation
photoionised gas at low expansion velocities. It represents a unique
astrophysical situation in which to search for hyperfine structure
(HFS) in coronal emission lines from highly ionised species. HFS is
otherwise blended by thermal or velocity broadening. Spectra
containing [AlVI] 3.66m
P
P
,
obtained with Phoenix on Gemini-South at resolving powers of up to
75000, resolve the line into five hyperfine components separated by 20
to 60 km
due to the coupling of the
nuclear spin of
Al with the total electronic angular momentum
.
Al
has a different nuclear spin of
, and a different HFS, which
allows us to place a 3
upper limit on the
Al/
Al
abundance ratio of 1/33. We measure the HFS magnetic-dipole coupling
constants for [AlVI], and provide the first estimates of the
electric-quadrupole HFS coupling constants obtained through
astronomical observations of an atomic transition.